A two-layer model for studying 2D dissolved pollutant runoff over impermeable surfaces

Dissolved pollutants in stormwater are a main contributor to water pollution in urban environments. However, many existing transport models are semi-empirical and only consider one-dimensional flows, which limit their predictive capacity. Combining the shallow water and the advection–diffusion equations, a two-dimensional physically based model is developed for dissolved pollutant transport by adopting the concept of a ‘control layer’. A series of laboratory experiments has been conducted to validate the proposed model, taking into account the effects of buildings and intermittent rainfalls. The predictions are found to be in good agreement with experimental observations, which supports the assumption that the depth of the control layer is constant. Based on the validated model, a parametric study is conducted, focusing on the characteristics of the pollutant distribution and transport rate over the depth. The hyetograph, including the intensity, duration and intermittency, of rainfall event has a significant influence on the pollutant transport rates. The depth of the control layer, rainfall intensity, surface roughness and area length are dominant factors that affect the dissolved pollutant transport. Finally, several perspectives of the new pollutant transport model are discussed. This study contributes to an in-depth understanding of the dissolved pollutant transport processes on impermeable surfaces and urban stormwater management.     

Drying increases organic colloidal mobilization in the karst vadose zone: Evidence from a 15-year cave-monitoring study

Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems.     

2020年1月19日新疆伽师MS6.4地震InSAR同震形变场特征及发震构造初步探讨

基于Sentinel-1 SAR升、降影像,利用D-InSAR技术获取新疆伽师M S6.4地震的同震形变场,结果表明,本次地震引起的同震形变场整体呈近椭圆状分布,形变区东西长约66 km,南北宽约40 km,整个形变场由南部隆升区和北部沉降区组成,南部最大隆升量约7 cm,北部最大沉降量约3 cm。本次地震发生在块体俯冲界面处的低倾角逆冲推覆构造带上,隆升和沉降两个中心均位于逆冲推覆体的上盘,形变主要以隆升形变为主,符合低倾角逆断层中强震的变形特征。在沉降区与隆升区之间干涉条纹连续分布,未出现表征地表破裂位置的空间失相关带,表明地震未引起明显的地表破裂。结合震源机制、余震精定位及区域构造特征,初步推断认为伽师地震的发震构造可能为柯坪塔格推覆构造前缘的N倾的柯坪断裂。     

三峡工程运用后坝下游河道泥沙输移变化规律

三峡工程蓄水后"清水"下泄,坝下游河段将会长期处于严重不饱和状态,水流含沙量沿程恢复将会引起坝下游长距离冲刷,本文根据三峡工程蓄水前、后的实测资料分析了坝下游河道泥沙输移变化规律,探索不同粒径组沙量沿程恢复对河床冲刷的影响,得到以下结论:在蓄水初期d≤0.031 mm沙量恢复主要受河床补给与江湖入汇共同的影响,随着水库下泄该粒径组沙量递减,使得各站该粒径组年均输沙量均远小于蓄水前的水平,沙量恢复仍主要受河床补给与江湖入汇的影响,这是造成坝下游河道发生长距离冲刷的主要原因之一;在蓄水初期0.031 mmd≤0.125 mm沙量恢复主要受河床补给的影响,但江湖入汇的影响较大,随着河床补给量逐渐减少,各站该粒径组年均输沙量均小于蓄水前的水平,沙量恢复仍主要受河床补给的影响,江湖入汇的影响逐渐减小,这也是坝下游河道发生长距离冲刷的主要原因之一; d0.125 mm沙量恢复主要受河床补给的影响,蓄水初期该粒径组沙量在宜昌监利河段沿程恢复速率较快,且在监利站达到蓄水前的水平,随着时间推移,在宜昌监利河段沿程恢复且速率仍较快,在监利站达到最大值,其数值逐渐小于蓄水前的水平,这是造成坝下游河道冲刷重点集中在宜昌监利河段的主要原因.     

Orbital control on cyclical organic matter accumulation in Early Silurian Longmaxi Formation shales

High resolution(939 samples)total organic carbon content(TOC)analyses were conducted on the Shuanghe Section of^152.6 m in the Changning area,Sichuan Basin.The sampling section was divided into two units considering the distinct-different deposit environment and sediments accumulation rate.The lower part(Unit 1)and the peer part(Unit 2)with high resolution sample spacing(0.08–0.4 m)enables the identification of the precession cycle in two sedimentary sequences with distinct different sedimentary accumulation rate.MTM Power spectral analyses on untuned TOC series reveals significant peaks exceeding above the 95%confidence level and shows that both Unit 1 and Unit 2 have recorded Milankovitch cycles of 405 kyr long eccentricity,short eccentricity,obliquity and precession.The floating astronomical time scale(ATS)was constructed on the Shuanghe Section in the Early Silurian(~439.673–444.681 Ma),and which was calibrated by 405 kyr long eccentricity cycles.The total duration of the Wufeng and Longmaxi shales is 5.01 Myr.The floating ATS used for estimating the duration of the graptolite zones and each stage in the study interval.Finally,we postulated two models that could verify the linkage between orbital cycle and organic accumulation.To make sure whether productivity or preservation is the main factor that under long eccentricity control,the phase correlation between the obtained filtered signal and the theoretical orbital solution should be made clear in the further research.     

绿色空间对休闲性体力活动影响的社区分异 ——以广州市为例

以广州市20个典型社区为例，构建多元线性回归模型，探讨了绿色空间对居民休闲性体力活动的影响，并剖析绿色空间对不同类型社区居民休闲性体力活动影响的作用机制。结果发现：1）不同类型社区居民的休闲性体力活动水平存在明显差异，低档社区的为782.99 MET-min/w，中档社区的为871.70 MET-min/w，高档社区的为1 227.91 MET-min/w；2）影响不同类型社区居民休闲性体力活动水平的绿色空间因素有所不同，低档社区、中档社区和高档社区的显著因子分别为“到最近公园广场距离”“邻里绿化覆盖率”和“健身活动设施数量”；3）绿色空间对休闲性体力活动水平影响的作用机制存在社区差异，低档社区居民休闲性体力活动主要受到成本作用的约束，中档社区居民主要受绿化环境作用影响，而高档社区居民主要受机会作用影响。     

以PAC为原料合成锂吸附剂的工艺研究

研究了聚合氯化铝(PAC)为原料合成锂吸附剂的基本工艺路线,并探究了加料方式、反应物配比、反应温度、反应时间和加料速度等对所合成吸附剂吸附量的影响,研究结果表明配比是影响吸附剂吸附量的最主要因素,得到了最佳合成条件,在此条件下所合成吸附剂对锂离子的吸附容量为6.1 mg/g。推断吸附剂的主要成分为晶态或非晶态的LiCl·2Al(OH)_3·nH_2O,同时含有Al(OH)_3、(CaO)_3Al_2O_3·6H_2O及LiCl·H_2O等成分。从吸附结果来看,结晶度较差的片状LiCl·2Al(OH)_3·nH_2O和非晶态的Al(OH)_3为主成分的吸附剂吸附性能最好。     

CG-6型重力仪零漂特性研究

对中国地震局地震研究所最新引进的4台CG-6型相对重力仪的零漂特性进行测试研究，结果表明，4台重力仪的静态零漂率、混合零漂率和动态零漂率均小于8 μGal/h，满足厂家给出的技术指标。在较长观测时间内，各台仪器的零漂均存在不同程度的非线性特征，因此在进行较长时间的野外观测以及后续数据处理中，不宜将零漂率作为常数进行解算和零漂改正。     

米氏凯伦藻细胞表面膜蛋白质组及其对温度变化的响应研究

米氏凯伦藻(Karenia mikimotoi)近年在我国福建、浙江和广东沿海经常形成赤潮,其赤潮不仅影响到海洋生态系统的稳定,也严重威胁到水产养殖以及人类生命健康安全。本论文以米氏凯伦藻为研究对象,建立了米氏凯伦藻细胞表面膜蛋白质荧光标记技术和细胞膜蛋白质提取方法,运用荧光差异凝胶电泳技术(2-DDIGE)对膜蛋白质进行了分析,并研究了米氏凯伦藻的膜蛋白质组及其对环境温度变动的响应。实验共鉴定到44个细胞表面膜蛋白,其中有效注释27个,主要为转运蛋白、HSP70蛋白家族和捕光蛋白等。米氏凯伦藻在20°C条件下的细胞生长和光合作用要明显好于16°C和12°C,但16°C和12°C条件下的差别不大,表明低温限制了米氏凯伦藻的生长。当米氏凯伦藻从12°C快速转移至16°C和20°C时,藻细胞密度和光合作用效率短时间迅速降低,但细胞很快即适应温度变化。细胞膜上的转运蛋白和光合作用蛋白在其适应温度变化中起着重要作用。     

长江河口潮波传播机制及阈值效应分析

河口潮波传播过程受沿程地形(如河宽辐聚、水深变化)及上游径流等诸多因素影响,时空变化复杂。径潮动力非线性相互作用研究有利于揭示河口潮波传播的动力学机制,对河口区水资源高效开发利用具有重要指导意义。本文基于2007—2009年长江河口沿程天生港、江阴、镇江、南京、马鞍山、芜湖的逐日高、低潮位数据及大通站日均流量数据,统计分析不同河段潮波衰减率与余水位坡度随流量的变化特征,结果表明潮波衰减率绝对值与余水位坡度随流量增大并不是单调递增,而是存在一个阈值流量和区域,对应潮波衰减效应的极大值。为揭示这一阈值现象,采用一维水动力解析模型对研究河段的潮波传播过程进行模拟。结果表明,潮波传播的阈值现象主要是由于洪季上游回水作用随流量加强,余水位及水深增大,导致河口辐聚程度减小,而余水位坡度为适应河口形状变化亦有所减小,从而形成相对应的阈值流量和区域。